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    • 专利摘要:
    Radial tire, in particular for passenger cars or vans, with a very thin belt structure (10) comprising a multilayer composite laminate (10a, 10b, 10c) of specific construction, with a first layer (10a) of rubber (C1) reinforced with reinforcements ( 110) circumferential fabrics in the form of monofilaments or assemblies of monofilaments, preferably weakly heat-shrinkable, for example nylon or polyester, this first layer radially overcoming (in the Z direction) two further layers (10b, 10c) of rubber (respectively C2, C3) reinforced with monofilaments (120, 130) of high strength steel. The average thickness of rubber, measured in the radial direction (Z), separating a first reinforcement (110) from the second reinforcement (120) which is closest thereto, as well as that separating a second reinforcement (120) from the third reinforcement ( 130) which are closest to it, are both less than or equal to 0.35 mm.
    公开号:FR3032149A1
    申请号:FR1550814
    申请日:2015-02-03
    公开日:2016-08-05
    发明作者:Camille Astaix；Aurore Lardjane
    申请人:Michelin Recherche et Technique SA Switzerland ；Compagnie Generale des Etablissements Michelin SCA；Michelin Recherche et Technique SA France；
    IPC主号:
    专利说明:

    [0001] FIELD OF THE INVENTION The present invention relates to tires for vehicles, and to their crown reinforcement or belt. It relates more particularly to multilayer composite laminates used in the belt of such tires, particularly for passenger cars or vans. 2. State of the art A radial carcass reinforcement tire for a passenger vehicle or a van has, as is known, a tread, two inextensible beads, two flexible flanks connecting the beads to the tread, and a rigid crown reinforcement. or "belt" (Wh ") disposed circumferentially between the carcass reinforcement and the tread.
    [0002] The tire belt is generally constituted by at least two rubber plies known as "working plies", "triangulation plies" or "working reinforcement", superimposed and crossed, most often reinforced with metal cables arranged substantially parallel to one another. relative to the others and inclined relative to the median circumferential plane, these working plies may or may not be associated with other plies and / or fabrics of rubber. These working plies have the primary function of giving the tire rigidity or high drift ("drift thrust" or "cornering"), necessary in a known manner to obtain good road handling ("handling"). ") on a motor vehicle.
    [0003] The above belt, which is particularly the case for tires likely to run at high speed in a sustained manner, may further comprise an additional rubber ply above the working plies (tread side), called " "hooping web" or "hooping reinforcement", which is generally reinforced by so-called "circumferential" reinforcing yarns, that is to say that these reinforcement yarns are arranged substantially parallel to one another and extend substantially circumferentially around the tire envelope so as to form an angle preferably within a range of -50 to +5 ° with the median circumferential plane. These circumferential reinforcing son have the primary function, it is recalled, to resist the centrifugation of the top at high speed. Such belt structures, ultimately consisting of a multilayer composite laminate comprising at least one hooping web, most often textile, and two generally metal working webs, are well known to those skilled in the art. do not need to be described here in more detail.
    [0004] The general state of the art describing such belt structures is illustrated in particular by the documents US Pat. No. 4,371,025, FR 2,504,067 or US Pat. No. 4,819,705, EP 738,615, EP 795,426 or US Pat. No. 5,858,137. 1,162,086 or US 2002/0011296, EP 1,184,203 or US 2002/0055583.
    [0005] The availability of increasingly resistant and long-lasting steels means that tire manufacturers are moving as far as possible towards use in belts of rope tires with a very simple structure, especially just two wires. even unitary filaments, in part to simplify manufacturing and reduce costs, on the other hand to reduce the thickness of the reinforcement plies and thus the hysteresis of the tires, ultimately reduce the consumption of energy from vehicles equipped with such tires. Efforts to reduce the mass of tires, in particular by reducing the thickness of their belts and the layers of rubber constituting them, are, of course, encountering physical limitations which may give rise to a certain number of difficulties. . In particular, it may occur that the hooping function provided by the hooping reinforcement and that of stiffening provided by the reinforcement are no longer sufficiently differentiated from one another and may be mutually interfering. This is detrimental to the proper functioning of the tire crown, the performance and the overall endurance of the tire. Thus, patent applications WO 2013/117476 and WO 2013/117477 filed by the Applicants have proposed a multilayer composite laminate with a specific structure which makes it possible to appreciably reduce the tire belt, and thus to reduce their resistance to rolling, while overcoming the disadvantages mentioned above. These applications disclose a radial tire, defining three main directions, circumferential, axial and radial, having a crown surmounted by a tread, two sidewalls, two beads, each side connecting each bead at the top, a carcass reinforcement anchored in each flanges and extending in the flanks and in the apex, a crown reinforcement or belt extending circumferentially in the circumferential direction and located radially between the carcass reinforcement and the tread, said belt comprising a laminate multilayer composite comprising at least three superimposed layers of reinforcement, said reinforcements being in each layer unidirectional and embedded in a rubber thickness, with in particular: o tread side, a first rubber layer having a first row; reinforcements, oriented at an alpha angle of -5 to +5 degrees from the directio n circumferential, these reinforcements said first reinforcements being heat shrink textile material; in contact with the first layer and disposed under the latter, a second rubber layer comprising a second row of reinforcements, oriented at a given angle beta, positive or negative, between 10 and 30 degrees with respect to the circumferential direction, these reinforcement said second reinforcements being metal reinforcements; in contact with the second layer and disposed beneath the latter, a third rubber layer comprising a third row of reinforcements, oriented at a gamma angle opposite the beta angle, itself between 10 and 30 degrees relative to the circumferential direction, said reinforcements said third reinforcements being metal reinforcements. The first reinforcements, preferably made of polyamide or polyester, consist of multifilament fibers comprising a very large number (typically several hundred) of elementary filaments of very small diameter, which are twisted together in the form of conventional textile ropes. The second and third reinforcements consist of unit monofilaments made of steel, in particular very high strength carbon steel.
    [0006] The above patent applications have demonstrated that it is possible, thanks to the specific construction of their multilayer composite laminate, in particular to the use of textile circumferential reinforcements whose heat shrinkability is controlled and metal reinforcements in the form of single unit monofilaments. small diameter, significantly reduce the overall thickness of the tire belts, and this without affecting the proper implementation and differentiation of functions on the one hand hooping provided by the circumferential reinforcements of the first layer, d on the other hand stiffening provided by the metal reinforcements of the other two layers.
    [0007] Thus, the weight of the tires and their rolling resistance can be reduced at reduced cost by using steel monofilaments that do not require any prior assembly operation, and this without penalizing the rigidity of drift or the overall endurance. rolling. P10-3531 - 4 - The objective of tire manufacturers, starting from the multilayer laminates described in the two above applications, to further reduce the thicknesses of the (first, second and third) rubber layers now faces the risk of generating in the radial direction (Z), here or there in the crown of the tire, direct contact between the reinforcements of these different layers, which would be detrimental to the proper functioning and endurance of the laminate. In particular, a direct contact between the circumferential textile reinforcements, which are known to naturally contain and are capable of transporting a certain quantity of water, which varies according to the nature of the heat-shrinkable textile material, and the steel monofilaments, could lead to term a surface corrosion of the latter, therefore a loss of strength, not to mention a risk of degradation of the adhesion with the surrounding rubber, ultimately a risk of reducing the overall endurance of the frame of work after prolonged rolling of the tires. 3. BRIEF DESCRIPTION OF THE INVENTION Continuing their research, the Applicants have developed an improved multilayer composite laminate, of new architecture, which answers the above problem and which may therefore be an advantageous alternative to the laminates described in both aforementioned applications, when it is desired to further reduce the thicknesses of the rubber layers and consequently the rolling resistance of the tires.
    [0008] Thus, according to a first object, the present invention relates (according to the references given in FIGS. 1 and 2 appended) to a radial tire (1), defining three main directions, circumferential (X), axial (Y) and radial (Z), having a top (2) surmounted by a tread (3), two sidewalls (4), two beads (5), each sidewall (4) connecting each bead (5) to the top (2), a carcass reinforcement (7) anchored in each of the beads (5) and extending in the flanks (4) to the top (2), a crown reinforcement or belt (10) extending into the top (2) in the direction circumferential (X) and located radially between the carcass reinforcement (7) and the tread (3), said belt (10) comprising a multilayer composite laminate (10a, 10b, 10c) comprising at least three superposed layers of reinforcements (110, 120, 130), said reinforcements being in each layer unidirectional and embedded in a thickness of rubber (res respectively C1, C2, C3), with: o tread side, a first layer (10a) of rubber (C1) having a first row of reinforcements (110), oriented at an angle alpha of -5 to +5 degrees P10 -3531 - 5 - relative to the circumferential direction (X), these reinforcements (110) said first reinforcements being made of heat-shrinkable textile material; in contact with the first layer (10b) and disposed under the latter, a second layer (10b) of rubber (C2) comprising a second row of reinforcements (120), oriented at a given beta angle, positive or negative, between 10 and 30 degrees relative to the circumferential direction (X), these reinforcements (120) said second reinforcements being metal reinforcements; o in contact with the second layer (10b) and disposed beneath the latter, a third layer (10c) of rubber (C3) comprising a third row of reinforcements (130), oriented at a gamma angle opposite to the angle beta, -Even between 10 and 30 degrees relative to the circumferential direction (X), these reinforcements (130) said third reinforcements being metal reinforcements, this tire being characterized in that: o the first reinforcements (110) made of heat-shrinkable textile material are monofilaments of diameter or thickness greater than 0.10 mm, or assemblies of such monofilaments; o the overall diameter noted Dl of the first reinforcements (110) is between 0.20 mm and 1.20 mm; the second (120) and third (130) reinforcements are steel monofilaments of diameter or thickness, respectively D2 and D3, of between 0.20 mm and 0.50 mm; the following characteristics, measured in the central part of the tire belt in the vulcanized state, on either side of the median plane (M) over a total axial width of 10 cm, are verified: the average thickness Ezi rubber separating a first reinforcement (110) of the second reinforcement (120) which is closest thereto, measured in the radial direction (Z), is less than or equal to 0.35 mm; - The average thickness Ez2 rubber separating a second reinforcement (120) of the third reinforcement (130) which is closest thereto, measured in the radial direction (Z), is less than or equal to 0.35 mm.
    [0009] The risks of corrosion or loss of adhesion mentioned above are significantly reduced in the laminate, thanks to the use of textile reinforcements (110) in the form of monofilaments of large diameter or assemblies of such monofilaments, in place of conventional textile strings based on multifilament fibers as described in WO 2013/117476 and WO 2013/117477 cited above.
    [0010] P10-3531 - 6 - The multilayer composite laminate according to the invention can be used as a belt reinforcing element of any type of tire, particularly for a passenger vehicle including in particular 4x4 vehicles and "SUV" (Sport Utility Vehicles) or for a van vehicle .
    [0011] The invention as well as its advantages will be readily understood in the light of the detailed description and the following exemplary embodiments, as well as FIGS. 1 to 4 relating to these examples, which schematize (unless otherwise indicated, without respecting a specific scale). ): - in radial section (that is to say in a plane containing the axis of rotation of the tire), an example of a tire (1) according to the invention, incorporating in its belt (10) a composite laminate multilayer according to the invention (Fig. 1); in cross-section, two examples of multilayer composite laminate (10a, 10b, 10c) used in the tire (1) according to the invention, using reinforcements (110) made of heat-shrinkable textile material respectively in the form of an assembly of monofilaments (Fig. 2) or unit monofilament (Fig. 3); in cross-section, various possible examples of assemblies of monofilaments (111) of heat-shrinkable textile material, which can be used as reinforcements (110) in the first layer (10a) of the multilayer composite laminate according to the invention (FIG. 4. DEFINITIONS In the present application, the following terms are used: - "rubber" or "elastomer" (both terms being considered synonymous): any type of elastomer, whether of the diene type or of the non-diene type, for example thermoplastic; "rubber composition" or "rubber composition" means a composition which comprises at least one rubber and a filler; - "layer": a sheet, strip or any other element of relatively small thickness relative to its other dimensions, preferably whose ratio of the thickness on the largest of the other dimensions is less than 0.5, more preferably less than 0.1; - "axial direction": a direction substantially parallel to the axis of rotation of the tire; "circumferential direction" means a direction that is substantially perpendicular both to the axial direction and to a radius of the tire (in other words, tangential to a circle whose center is on the axis of rotation of the tire); "radial direction" means a direction along a radius of the tire, that is to say any direction passing through the axis of rotation of the tire and substantially perpendicular to that direction; that is to say, making with a perpendicular to this direction an angle not diverging by more than 5 degrees; - "monofilament" or indistinctly "monofil", in general, any unit filament, whatever the shape of its cross section, whose diameter (case of a circular cross section) or the thickness (case of a section right non-circular) are greater than 100 1.1.m. This definition covers both substantially cylindrical monofilaments (circular cross section) and monofilaments of different shape, for example oblong monofilaments (flattened shape), or rectangular or square cross section; - "oriented along an axis or a direction" while speaking of any element such as a reinforcement, an element which is oriented substantially parallel to this axis or this direction, that is to say doing with this axis or this direction an angle not deviating by more than 5 degrees (therefore zero or at most equal to 5 degrees); - "oriented perpendicular to an axis or direction": speaking of any element such as a reinforcement, an element that is oriented substantially perpendicular to that axis or direction, that is to say, with a perpendicular at that axis or direction an angle not diverging by more than 5 degrees; - "median circumferential plane" (denoted M): the plane perpendicular to the Y axis of rotation of the tire which is located midway between the two beads and passes through the middle of the crown reinforcement or belt; - "reinforcement" or "reinforcing thread": any long and thin strand that is to say filiform, elongate, of great length relative to its cross section, especially any unitary filament, any multifilament fiber or any assembly of such filaments or fibers such as a plied yarn or cable, this strand or yarn being rectilinear as non-rectilinear, for example twisted, or corrugated, such yarn or yarn being capable of reinforcing a rubber matrix (i.e. increase the tensile properties of the matrix); - "Unidirectional reinforcements": reinforcements substantially parallel to each other, that is to say oriented along the same axis; - "laminate" or "multilayer laminate": within the meaning of the International Patent Classification, any product having at least two layers, of flat or non-planar shape, in contact with each other, which may be or unrelated, connected to each other; the term "bound" or "connected" must be interpreted extensively to include all connecting or joining means, in particular by gluing.
    [0012] On the other hand, unless expressly indicated otherwise, all the percentages (%) indicated are% by mass. The expression "x and / or y" means "x" or "y" or both (i.e., "x and y"). Any range of values designated by the expression "between a and b" represents the range of values from more than "a" to less than "b" (i.e., "a" and "b" terminals excluded ) while P10-3531 - 8 - any range of values referred to as "a to b" means the range of values from "a" to "b" (i.e., including strict bounds "a" and "b"). 5. DETAILED DESCRIPTION AND EXAMPLES OF CARRYING OUT THE INVENTION By way of example, FIG. 1 very schematically represents (that is to say, without respecting a specific scale) a radial section of a compliant tire. to the invention, for example for tourism-type vehicle or van, whose belt comprises a multilayer composite laminate according to the invention. This tire (1) according to the invention, defining three perpendicular, circumferential (X), axial (Y) and radial (Z) directions, comprises an apex (2) surmounted by a tread (3), two sidewalls (4), two beads (5), each flank (4) connecting each bead (5) to the top (2), a carcass reinforcement (7) anchored in each of the beads (5) and extending into the flanks ( 4) to the top (2), a crown reinforcement or belt (10) extending in the crown (2) in the circumferential direction (X) and radially between the carcass reinforcement (7) and the web rolling (3). The carcass reinforcement (7) is in a known manner constituted by at least one rubber ply reinforced by so-called "radial" textile cords arranged substantially parallel to each other and extending from one bead to the other so as to form an angle generally between 80 ° and 90 ° with the median circumferential plane M; it is here, for example, wrapped around two rods (6) in each bead (5), the upturn (8) of this armature (7) being for example disposed towards the outside of the tire (1) which is shown here mounted on its rim (9). According to the present invention, in accordance with the representations of Figures 2 and 3 which will be detailed later, the belt (10) of the tire (1) comprises a multilayer composite laminate comprising three layers (10a, 10b, 10c) superimposed reinforcements, said reinforcements being in each unidirectional layer and embedded in a thickness of rubber (respectively Cl, C2, C3), with: o tread side, a first layer (10a) of rubber (Cl) having a first row of reinforcements (110), oriented at an angle alpha of -5 to +5 degrees with respect to the circumferential direction (X), these reinforcements (110) said first reinforcements being made of heat-shrinkable textile material; in contact with the first layer (10b) and disposed under the latter, a second layer (10b) of rubber (C2) comprising a second row of reinforcements (120), oriented at a given beta angle, positive or negative, between 10 and 30 degrees relative to the circumferential direction (X), these reinforcements (120) said second reinforcements being metal reinforcements; o in contact with the second layer (10b) and disposed beneath the latter, a third layer (10c) of rubber (C3) comprising a third row of reinforcements (130), oriented at a gamma angle opposite to the angle beta, even between 10 and 30 degrees with respect to the circumferential direction (X), identical to or different from the angle beta, these reinforcements (130) said third reinforcements being metal reinforcements. According to the invention, the angles p and 'y of opposite directions, both between 100 and 30 °, may be identical or different, that is to say that the second (120) and third (130) reinforcements may be arranged symmetrically or not, on either side of the median circumferential plane (M) previously defined. In this tire shown schematically in Figure 1, it will be understood of course that the tread (3), the multilayer laminate (10) and the carcass reinforcement (7) may or may not be in contact with each other, even if these parts have been voluntarily separated in Figure 1, schematically, for reasons of simplicity and clarity of the drawing. They could be physically separated, at least for a part of them, for example by bonding gums, well known to those skilled in the art, intended to optimize the cohesion of the assembly after baking or crosslinking. According to a first essential characteristic of the invention, the first reinforcements (110) of heat-shrinkable textile material are monofilaments or assemblies of monofilaments, such monofilaments taken individually having a diameter (or, by definition, a thickness if the monofilament does not). is not substantially circular in cross-section) noted cp which is greater than 0.10 mm, preferably between 0.15 and 0.80 mm, in particular between 0.20 and 0.60 mm. The overall diameter (average) D1 of these first textile reinforcements (110) is meanwhile between 0.20 mm and 1.20 mm, preferably between 0.30 and 1.00 mm, in particular between 0, 40 and 0.80 mm; in other words, in the particular case where the reinforcement (110) consists of a unitary monofilament unit of circular cross section, the latter has a diameter cp which is necessarily greater than 0.20 mm. The diameter of the cylinder of imaginary revolution which surrounds such first textile reinforcements (110) in the general case where they are not circular in cross section is usually understood as the overall diameter. Any heat-shrinkable textile material is suitable, in particular and preferably a textile material satisfying the contraction characteristics CT set forth below is suitable. This heat-shrinkable textile material is preferably chosen from the group consisting of polyamides, polyesters and polyketones. Among the polyamides that may be mentioned in particular are polyamides 4-6, 6, 6-6, 11 or 12. Among the polyesters that may be mentioned for example PET (polyethylene terephthalate), PEN (polyethylene naphthalate), PBT (polybutylene terephthalate) ), PBN (polybutylene naphthalate), PPT (polypropylene terephthalate), PPN (polypropylene naphthalate). Are also usable, particularly and preferably to the extent that they verify the characteristic CT recommended above, hybrid reinforcements consisting of two (at least two) different materials such as for example aramid / nylon, aramid / polyester monofilament assemblies aramid / polyketone.
    [0013] More preferably, the heat-shrinkable textile material constituting the first reinforcements (110) is a polyamide (nylon) or a polyester. The density d1 of the first reinforcements (110) in the first rubber layer (C1), measured in the axial direction (Y), is preferably between 70 and 130 threads / dm, more preferably between 80 and 120 threads / dm. , in particular between 90 and 110 threads / dm. Their thermal contraction (denoted CT), after 2 min at 185 ° C., is preferably less than 7.5%, more preferably less than 7.0%, in particular less than 6.0%, which values have proved preferable. for the stability of manufacture and dimensioning of the tire casings, in particular during the phases of cooking and cooling of the latter. This is the relative contraction of these first reinforcements (110) under the conditions described hereinafter of the test. The quantity CT is measured, except for different precisions, according to the ASTM D1204-08 standard, for example on a device of the "TESTRITE" type, under a so-called standard pretension of 0.5 cN / tex (thus reduced to the title or linear density of the sample tested). At constant length, the maximum of the contraction force (denoted FO) is also measured using the above test, this time at a temperature of 180 ° C. and under 3% of elongation.
    [0014] This contraction force Fc is preferably greater than 20 N (Newton). A high contraction force proved to be particularly favorable to the hooping capacity of the first reinforcements (110) of heat-shrinkable textile material, vis-à-vis the crown reinforcement of the tire when the latter heats up under high speed rolling.
    [0015] The quantities CT and Fc above can be indistinctly measured on the initial textile reinforcements glued before their incorporation into the laminate and then into the tire, or else measured on these reinforcements once extracted from the central zone of the vulcanized tire and preferably "degummed" "(That is to say, freed of the rubber which coats them in the layer C1).
    [0016] P10-3531 FIG. 4 schematizes in cross-section various examples (112, 113, 114, 115, 116, 117) of assemblies of (respectively 2, 3, 4, 5, 6 and 7) monofilaments (111) of material heat-shrinkable textile such as for example polyamide, polyester or polyketone, usable as reinforcements (110) in the first layer (10a) of the multilayer composite laminate according to the invention. Such assemblies and their methods of manufacture are well known to those skilled in the art; they have been described in numerous patent documents, by way of examples FR 1 495 730, FR 2 022 643 or US 3 638 706, FR 2 577 478 or US Pat. No. 4,724,881, EP 500,480 or US Pat. No. 5,442,903.
    [0017] EP 517,870 or US 5,427,165, WO 2010/143017, or in publications such as "Investigation of twisted monofilament cord properties made of nylon 6.6 and polyester," B. Yilmaz, Fibers and Polymers 2011, vol. 12, No. 8, 1091-1098. The monofilaments or assemblies of heat-shrinkable textile monofilaments have the advantage, compared to textile ropes formed of conventional multifilament fibers, to better protect against moisture the rest of the multilayer composite laminate, thus limiting the risks of penalizing the adhesion between the various reinforcements of the laminate and their surrounding rubber matrix, not to mention the risks of surface corrosion of steel monofilaments.
    [0018] If assemblies of textile monofilaments are used, they preferably comprise 2 to 10, more preferably 3 to 7 monofilaments of heat-shrinkable textile material such as for example polyamide, polyester or polyketone. For the manufacture of these assemblies, the monofilaments are cabled, twisted together according to well-known techniques, with a twist preferably between 30 and 200 rev / m (revolutions per meter), more preferably between and 100 rev / m, these monofilaments being in a known manner, lacking, or almost devoid of, torsion on themselves. The second (120) and third (130) reinforcements consist of steel monofilaments, which as a reminder are not twisted, wired together but used in the unitary state; their diameter (or by definition thickness if the monofilament does not have a circular cross section), respectively denoted D2 and D3, is between 0.20 mm and 0.50 mm. D2 and D3 may be the same or different from one layer to another; if they are different, D3 may be greater than D2 or less than D2, depending on the particular embodiments of the invention.
    [0019] More preferably, for optimum endurance of the tire of the invention, especially under severe driving conditions, it is preferred that D2 and D3 are greater than 0.25 mm and less than 0.40 mm, more preferably included in a range of 0.28 to 0.35 mm. P10-3531 - 12 - The density, denoted respectively d2 and d3, of the second (120) and third (130) reinforcements in respectively the second (C2) and third (C3) rubber layers, measured in the axial direction (Y) , is preferably between 100 and 180 son / dm, more preferably between 110 and 170 son / dm, in particular between 120 and 160 son / dm.
    [0020] Preferably, the steel of the monofilaments is a carbon steel such as those used in the "steel cords" type cables for tires; but it is of course possible to use other steels, for example stainless steels, or other alloys.
    [0021] According to a preferred embodiment, when a carbon steel is used, its carbon content (% by weight of steel) is in a range of 0.5% to 1.2%, more preferably 0.7%. % to 1.0%. The invention applies in particular to steels of the steel cord type with normal resistance (called "NT" for "Normal Tensile") or with high resistance (called "HT" for "High Tensile"), the (second and third ) reinforcing carbon steel then having a tensile strength (Rm) which is preferably greater than 2000 MPa, more preferably greater than 2500 MPa. The invention also applies to steels of the steel cord type with very high strength (called "SHT" for "Super High Tensile"), ultra-high strength (called "UHT" for "Ultra High Tensile" or "MT" for "Mega Tensile"), the (second and third) carbon steel reinforcements then having a tensile strength (Rm) which is preferably greater than 3000 MPa, more preferably greater than 3500 MPa. The total elongation at break (Δt) of these reinforcements, sum of the elastic elongation and the plastic elongation, is preferably greater than 2.0%. For reinforcements (second and third) in steel, tensile strength, tensile strength Rm (in MPa) and elongation at break noted At (total elongation in%) are measured. in tension according to the ISO 6892 standard of 1984. The steel used, whether it is in particular a carbon steel or a stainless steel, may itself be coated with a metallic layer improving, for example the properties of implementation of the steel monofilament, or the properties of use of the reinforcement and / or of the tire themselves, such as the properties of adhesion, corrosion resistance or resistance to aging. According to a preferred embodiment, the steel used is covered with a layer of brass (Zn-Cu alloy) or zinc; it is recalled that during the wire manufacturing process, the coating of brass or zinc facilitates the drawing of the wire, as well as the bonding of the wire with the rubber. But the reinforcements could be covered with a thin metal layer other than brass or zinc, whose function, for example, is to improve the corrosion resistance of these wires and / or their adhesion to the rubber, for example a thin layer of Co, Ni, Al, an alloy of two or more compounds Cu, Zn, Al, Ni, Co, Sn.
    [0022] Each layer (C1, C2, C3) of rubber composition (or hereinafter "rubber layer") constituting the multilayer composite laminate, is based on at least one elastomer and a filler.
    [0023] Preferably, the rubber is a diene rubber, that is to say for all elastomeric recall (single elastomer or elastomer mixture) which is derived, at least in part (ie, a homopolymer or a copolymer), monomers dienes that is to say monomers bearing two carbon-carbon double bonds, whether the latter are conjugated or not.
    [0024] This diene elastomer is more preferably selected from the group consisting of polybutadienes (BR), natural rubber (NR), synthetic polyisoprenes (IR), butadiene copolymers, isoprene copolymers, and mixtures of these elastomers. such copolymers being especially chosen from the group consisting of butadiene-styrene copolymers (SBR), isoprene-butadiene copolymers (BIR), isoprene-styrene copolymers (SIR) and isoprene-copolymers. butadiene-styrene (SBIR). A particularly preferred embodiment consists in using an "isoprene" elastomer, that is to say a homopolymer or a copolymer of isoprene, in other words a diene elastomer chosen from the group consisting of natural rubber (NR ), the synthetic polyisoprenes (IR), the various isoprene copolymers and the mixtures of these elastomers. The isoprene elastomer is preferably natural rubber or synthetic polyisoprene of the cis-1,4 type. Among these synthetic polyisoprenes, polyisoprenes having a content (mol%) of cis-1,4 bonds greater than 90%, more preferably still greater than 98%, are preferably used. According to a preferred embodiment, each layer of rubber composition comprises 50 to 100 phr of natural rubber. According to other preferred embodiments, the diene elastomer may consist, in whole or in part, of another diene elastomer such as, for example, an SBR elastomer used in or with another elastomer, for example type BR. Each rubber composition may comprise one or more diene elastomer (s), also all or part of the additives normally used in rubber matrices for the manufacture of tires, such as, for example, reinforcing fillers such as black rubber. carbon or silica, coupling agents, anti-aging agents, antioxidants, plasticizers or extension oils, whether these are aromatic or non-aromatic in nature (in particular very low or non-aromatic oils, for example of the naphthenic or paraffinic type, with high or preferably low viscosity, MES or TDAE oils), plasticizing resins with a high glass transition temperature (greater than 30 ° C.), P10-3531 - 14 facilitating agents. - work (processability) of the compositions in the green state, tackifying resins, anti-eversion agents, acceptors and methylene donors te As for example HMT (hexamethylenetetramine) or H3M (hexamethoxymethylmelamine), reinforcing resins (such as resorcinol or bismaleimide), known adhesion promoter systems of the metal salt type, for example, in particular salts of cobalt, nickel or lanthanide. , a crosslinking or vulcanization system. Preferably, the crosslinking system of the rubber composition is a so-called vulcanization system, that is to say based on sulfur (or a sulfur-donor agent) and a primary vulcanization accelerator. To this basic vulcanization system may be added various known secondary accelerators or vulcanization activators. The sulfur is used at a preferential rate of between 0.5 and 10 phr, the primary vulcanization accelerator, for example a sulfenamide, is used at a preferential rate of between 0.5 and 10 phr. The level of reinforcing filler, for example carbon black and / or silica, is preferably greater than 30 phr, especially between 30 and 100 phr. Carbon blacks are suitable for all carbon blacks, in particular blacks of the HAF, ISAF, SAF type conventionally used in tires (so-called pneumatic grade blacks). Among the latter, mention will be made more particularly of carbon blacks of (ASTM) grade 300, 600 or 700 (for example N326, N330, N347, N375, N683, N772). Suitable silicas are in particular precipitated or pyrogenic silicas having a BET surface area of less than 450 m 2 / g, preferably from 30 to 400 m 2 / g. Those skilled in the art will know, in the light of the present description, adjust the formulation of the rubber compositions in order to achieve the desired levels of properties (in particular modulus of elasticity), and adapt the formulation to the specific application considered. Preferably, each rubber composition has, in the crosslinked state, a secant modulus in extension, at 10% elongation, which is between 4 and 25 MPa, more preferably between 4 and 20 MPa; values in particular between 5 and 15 MPa have proved particularly suitable. The modulus measurements are carried out in tension, unless otherwise indicated according to ASTM D 412 of 1998 (specimen "C"): the secant modulus is measured in second elongation (that is to say after an accommodation cycle). "true" (that is to say, brought back to the actual section of the test piece) at 10% elongation, noted here Ms and expressed in MPa (normal temperature and humidity conditions according to standard ASTM D 1349 of 1999). To adhere the first, second and third reinforcements to their three respective rubber layers (C1, C2, C3) previously described, any suitable P10-3531 - 15 adhesive system may be used, for example a textile glue of the "RFL" type. "(resorcinol-formaldehyde) or equivalent with regard to the first textile reinforcements, or for example an adhesive coating such as brass or zinc with regard to the second and third steel reinforcements; however, it is also possible to use a clear steel, that is to say uncoated steel. On the other hand, the following essential characteristics, measured in the central part of the tire belt in the vulcanized state, on either side of the median plane (M) over a total axial width of 10 cm, are verified: - The average thickness Ezi rubber separating a first reinforcement (110) of the second reinforcement (120) which is closest thereto, measured in the radial direction (Z), is less than or equal to 0.35 mm; - The average thickness Ez2 rubber separating a second reinforcement (120) of the third reinforcement (130) which is closest thereto, measured in the radial direction (Z), is less than or equal to 0.35 mm. According to a preferred embodiment of the invention, at least one of the following characteristics is verified (more preferably all): Ezi is between 0.10 and 0.30, more preferably between 0.15 and 0.30 mm ; Ez2 is between 0.15 and 0.35, more preferably between 0.25 and 0.35 mm; - The total thickness of the multilayer composite laminate, that is to say its three layers (C1, C2, C3) superimposed, measured in the radial direction Z, is between 1.8 and 2.7 mm. All the data previously indicated (Dl, D2, D3, d1, d2, d3, Ezi, Ez2 and total thickness) are average values measured experimentally by an operator on photographs of radial cuts of vulcanized tires, operated in the central part of the belt, 5 cm on either side of the median plane (M), or on a total width of 10 cm (or between - 5 cm and + 5 cm with respect to the median plane M). Figures 2 and 3 show schematically (without respect of a specific scale), in cross-section, two examples of multilayer composite laminate (10a, 10b, 10c) used as a belt (10) in the tire (1) according to the invention of Figure 1, the laminate (10) using reinforcements (110) of heat-shrinkable textile material respectively in the form of an assembly of three monofilaments (Figure 2) or a single monofilament unit (Figure 3). ). P10-3531 - 16 - As illustrated in FIGS. 2 and 3, Ezi is the average of the thicknesses (Ezi (I), Ezi (2), Ezi (3), Eziw) of rubber separating a first reinforcement (110) from the second reinforcement (120) which is closest to it, these thicknesses being each measured in the radial direction Z, and averaged over a total axial distance of between - 5.0 cm and + 5.0 cm with respect to the center of the belt (ie , for example in total about 100 measurements if there are ten reinforcements (110) per cm in the layer C1). Expressed otherwise, Ezi is the average of the minimum distances Eziw separating "back to back" each first reinforcement (110) of the second reinforcement (120) that is closest to it in the radial direction Z, this average being calculated over all first reinforcements (110) present in the central part of the belt, in an axial gap extending between - 5 cm and + 5 cm with respect to the median plane M. Similarly, Ez2 is the average of the rubber thicknesses (Ez2 ( 1), Ez2 (2), Ez2 (3), - - - Ez2 (0) separating a second reinforcement (120) from the third reinforcement (130) which is closest to it, measured in the radial direction Z, this average being calculated on a total axial distance of between - 5.0 cm and + 5.0 cm from the center of the belt, expressed differently, these thicknesses represent the minimum distances between "back to back" the second reinforcement (120) of the third reinforcement (130) which is closest to it in the radi direction Z. Expressed differently, Ez2 is the average of the minimum distances Ez2 () separating "back to back" each second reinforcement (120) from the third reinforcement (130) which is closest to it in the radial direction Z, this average being calculated on all the second reinforcements (120) present in the central part of the belt, in an axial gap extending between -5 cm and + 5 cm with respect to the median plane M. For optimized performance in terms of resistance to rolling, drifting thrust and rolling endurance, the tire of the invention preferably satisfies at least one of the following inequalities (more preferably the three): 0.15 <Ezi / (Ezi + D1 + D2) <0.35 0, <Ez2 / (Ez2 + D2 + D3) <0.45 0.20 <(Ezi + Ez2) / (E1 + Ez2 + D1 + D2 + D3) <0.40.
    [0025] More preferably still, the tire of the invention preferably satisfies at least one of the following inequalities (more preferably all three): P10-3531 - 0.20 <Ezi / (Ezi + D1 + D2) <0.30 0, <Ez2 / (Ez2 + D2 + D3) <0.40 0.25 <(Ezi + Ez2) / (E1 + Ez2 + D1 + D2 + D3) <0.35.
    [0026] In conclusion, the invention offers the possibility of further reducing the thickness of the tire belts and that of the rubber layers constituting part of their structure, ultimately the weight and the rolling resistance of the tires, thanks to the use in its first layer of monofilaments or assemblies of thermofractile textile monofilaments. P10-3531
    权利要求:
    Claims (18)
    [0001]
    REVENDICATIONS1. Radial tire (1), defining three main directions, circumferential (X), axial (Y) and radial (Z), comprising a crown (2) surmounted by a tread (3), two sidewalls (4), two bead (5), each flank (4) connecting each bead (5) to the top (2), a carcass reinforcement (7) anchored in each of the beads (5) and extending in the flanks (4) to vertex (2), a crown reinforcement or belt (10) extending in the crown (2) in the circumferential direction (X) and radially between the carcass reinforcement (7) and the tread (3) said belt (10) comprising a multilayer composite laminate (10a, 10b, 10c) comprising at least three superposed layers of reinforcements (110, 120, 130), said reinforcements being in each layer unidirectional and embedded in a rubber thickness (respectively C1, C2, C3), with: o tread side, a first layer (10a) of rubber (Cl) comprising a first re row reinforcements (110) oriented at an angle alpha from -5 to +5 degrees to the circumferential direction (X), these reinforcements (110) said first reinforcing elements being made of textile material thermorétractile; in contact with the first layer (10b) and disposed under the latter, a second layer (10b) of rubber (C2) comprising a second row of reinforcements (120), oriented at a given beta angle, positive or negative, between 10 and 30 degrees relative to the circumferential direction (X), these reinforcements (120) said second reinforcements being metal reinforcements; o in contact with the second layer (10b) and disposed beneath the latter, a third layer (10c) of rubber (C3) comprising a third row of reinforcements (130), oriented at a gamma angle opposite to the angle beta, -Even between 10 and 30 degrees relative to the circumferential direction (X), these reinforcements (130) said third reinforcements being metal reinforcements, characterized in that: o the first reinforcements (110) heat-shrinkable textile material are monofilaments of diameter or thickness cp greater than 0.10 mm, or assemblies of such monofilaments; o the overall diameter noted Dl of the first reinforcements (110) is between 0.20 mm and 1.20 mm; the second (120) and third (130) reinforcements are steel monofilaments of diameter or thickness, respectively D2 and D3, of between 0.20 mm and 0.50 mm; P10-3531-19- the following characteristics, measured in the central part of the belt of the vulcanized tire, on either side of the median plane (M) over a total axial width of 10 cm, are verified the average thickness Ezi of rubber separating a first reinforcement (110) from the second reinforcement (120) which is closest to it, measured in the radial direction (Z), is less than or equal to 0.35 mm; - The average thickness Ez2 rubber separating a second reinforcement (120) of the third reinforcement (130) which is closest thereto, measured in the radial direction (Z), is less than or equal to 0.35 mm.
    [0002]
    2. A tire according to claim 1, wherein the diameter cp is between 0.15 mm and 0.80 mm, preferably between 0.20 and 0.60 mm.
    [0003]
    3. A tire according to any one of claims 1 or 2, wherein D1 is between 0.30 mm and 1.00 mm, preferably between 0.40 mm and 0.80 mm.
    [0004]
    A tire according to any one of claims 1 to 3, wherein the density of first reinforcements (110) in the first rubber layer (C1), measured in the axial direction (Y), is between 70 and 130 son / dm.
    [0005]
    Tire according to claim 4, wherein the density d1 is between 80 and 120, preferably between 90 and 110 son / dm.
    [0006]
    A tire according to any one of claims 1 to 5, wherein D2 and D3 are each greater than 0.25 mm and less than 0.40 mm, preferably within a range of 0.28 to 0.35 mm. .
    [0007]
    7. A tire according to any one of claims 1 to 6, wherein the density, respectively d2 and d3, of the second (120) and third (130) reinforcements in the second (C2) and third (C3) rubber layers respectively. , measured in the axial direction (Y), is between 100 and 180 threads / dm.
    [0008]
    8. The tire of claim 7, wherein the densities d2 and d3 are each between 110 and 170, preferably between 120 and 160 son / dm.
    [0009]
    9. A tire according to any one of claims 1 to 8, wherein the thermal contraction CT of the first reinforcements (110) of heat-shrinkable textile material after 2 min at 185 ° C is less than 7.5%. P10-3531- 20 -
    [0010]
    The tire of claim 9, wherein CT is less than 7.0%, preferably less than 6.0%.
    [0011]
    Tire according to any one of claims 1 to 10, wherein Ezi is between 0.10 and 0.30 mm, preferably between 0.15 mm and 0.30 mm.
    [0012]
    12. A tire according to any one of claims 1 to 11, wherein Ez2 is between 0.15 and 0.35 mm, preferably between 0.25 mm and 0.35 mm.
    [0013]
    13. A tire according to any one of claims 1 to 12, wherein the following inequality is verified: 0.15 <Ezi / (Ezi + D1 + D2) <0.35
    [0014]
    14. A tire according to any one of claims 1 to 13, wherein the following inequality is verified: 0.25 <Ez2 / (Ez2 + D2 + D3) <0.45
    [0015]
    15. A tire according to any one of claims 1 to 14, wherein the following inequality is verified: 0.20 <(Ezi + Ez2) / (Ezi + Ez2 + D1 + D2 + D3) <0.40
    [0016]
    16. A tire according to any one of claims 1 to 15, wherein the constituent steel of the second and third reinforcements (120, 130) is a carbon steel.
    [0017]
    17. A tire according to any one of claims 1 to 16, wherein the heat-shrinkable textile material constituting the first reinforcements (110) is a polyamide or a polyester.
    [0018]
    18. A tire according to any one of claims 1 to 17, wherein the first reinforcements (110) of heat-shrinkable textile material are assemblies of 2 to 10, preferably 3 to 7 monofilaments. P10-3531
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    同族专利:
    公开号 | 公开日
    CN107257742A|2017-10-17|
    CN107257742B|2019-09-13|
    FR3032149B1|2017-02-17|
    WO2016124419A1|2016-08-11|
    JP2018508405A|2018-03-29|
    EP3253592A1|2017-12-13|
    EP3253592B1|2020-06-03|
    US20180022159A1|2018-01-25|
    引用文献:
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    WO2013117477A1|2012-02-09|2013-08-15|Compagnie Generale Des Etablissements Michelin|Radial tyre with lightened belt structure|
    WO2013117476A1|2012-02-09|2013-08-15|Compagnie Generale Des Etablissements Michelin|Radial tyre with lightened belt structure|WO2017072151A1|2015-10-27|2017-05-04|Compagnie Generale Des Etablissements Michelin|Pneumatic tire, having working layers comprising monofilaments and a tire tread with grooves|
    WO2017072139A1|2015-10-27|2017-05-04|Compagnie Generale Des Etablissements Michelin|Pneumatic tire, having working layers comprising monofilaments and a tire tread with grooves|
    WO2017072136A1|2015-10-27|2017-05-04|Compagnie Generale Des Etablissements Michelin|Pneumatic tire, having working layers comprising monofilaments and a tire tread with incisions|
    WO2017072142A1|2015-10-27|2017-05-04|Compagnie Generale Des Etablissements Michelin|Pneumatic tire, having working layers comprising monofilaments and a tire tread with grooves|
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    法律状态:
    2016-02-18| PLFP| Fee payment|Year of fee payment: 2 |
    2016-08-05| PLSC| Search report ready|Effective date: 20160805 |
    2017-02-17| PLFP| Fee payment|Year of fee payment: 3 |
    2018-02-23| PLFP| Fee payment|Year of fee payment: 4 |
    2019-10-25| ST| Notification of lapse|Effective date: 20191006 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1550814A|FR3032149B1|2015-02-03|2015-02-03|RADIAL TIRE HAVING A VERY FINE BELT STRUCTURE|FR1550814A| FR3032149B1|2015-02-03|2015-02-03|RADIAL TIRE HAVING A VERY FINE BELT STRUCTURE|
    US15/547,986| US20180022159A1|2015-02-03|2016-01-22|Radial tire having a very thin belt structure|
    EP16701181.6A| EP3253592B1|2015-02-03|2016-01-22|Radial tyre having a very thin belt structure|
    PCT/EP2016/051305| WO2016124419A1|2015-02-03|2016-01-22|Radial tyre having a very thin belt structure|
    JP2017540995A| JP2018508405A|2015-02-03|2016-01-22|Radial tire with very thin belt structure|
    CN201680008382.XA| CN107257742B|2015-02-03|2016-01-22|Radial with very thin belt structure|
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